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The expressions free from and free of both refer to being delivered from something.
As a general rule, use free from when it can be replaced by "released from" in a sentence.
Use free of when it can be replaced by "relieved of."
Choosing between the prepositions from and of is sometimes a question of interpretation. For example, one may be free from the daily grind (i.e. released from it) or free of the daily routine (i.e. relieved of it), depending on the writer’s point of view.
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